Nga kupu kupu Ingarihi: ci37500;ciazoiccouplingcomponent1;cideveloper5;ChemicalbookDeveloperA;DeveloperAMS;DeveloperBN;developera;developerams

Tau CAS: 135-19-3
tātai rāpoi: C10H8O
Te taumaha ngota: 144.17
Nama EINECS: 205-182-7

Ngā kāwai e pā ana:

Wawaotanga; alomaticcoms; kaiwhakaputa, hononga; kaiwhakawhanake; biochefincens; poikiri; poikiri;

Te whakamahi 2-naphthol me te tikanga whakahiato

Āhuatanga matū:he tawerewere kanapa ma, he paura ma ranei.Karekau ki te wai, te wairewa ki te waiwaro, te etera, te chloroform, te glycerin me te wairewa alkali.

Whakamahia:
1. Ka whakamahia i roto i te whakarite i te waikawa Tobias, te waikawa J, te waikawa 2,3 me nga tae azo, a he mea ano hoki mo nga antioxidants rapa, nga kaihoko tukatuka kohuke, nga fungicides, nga antifungal agents, preservatives, etc.
2. Hei tiaki, ka whakatauhia e taku whenua ka taea te whakamahi mo te tiaki citrus, ko te nui o te whakamahinga ko te 0.1g / kg, a ko te toenga kaore e neke atu i te 70mg / kg.
3. Ko te Ethylnaphthol, e mohiotia ana ko te β-naphthol me te 2-naphthol, he takawaenga o te waikawa naphthoxyacetic tipu tipu.
4. Ka whakamahia hei tiaki kai.E ai ki to tatou whenua, ka taea hoki te whakamahi mo te tiaki citrus.Ko te nui o te whakamahinga ko te 0.1g/kg, a ko te toenga o te moni kaore e neke atu i te 70mg/kg.
5. Ka whakamahia hei reagent tātari, ethylene, waro monoxide absorbent me te tohu kare
6. He mea nui nga rauemi mata waro me nga waikano takawaenga, whakamahia i roto i te hanga o te waikawa Toubic, te waikawa butyric, te waikawa β-naphthol-3-carboxylic, ka whakamahia i roto i te hanga o te kaihoko anti-pakeke D, te kaihoko anti-aging DNP me etahi atu anti. -nga maatete tawhito, nga whakangao pararopi me nga patu patu tatari.
7. I whakamahia ki te whakarite i te waikawa Tobias, te waikawa J, te 2.3-waikawa, ka whakamahia i roto i te whakaritenga o te kaihoko anti-pakeke D, te kaihoko anti-pahekeheke DNP me ona kaihoko anti-pakeke, nga pigments organic me te fungicides
8. Manatokonga o bromine, chlorine, chlorate, niobium, parahi, nitrite me te pāhare pāporo.Fluorescence Chemicalbook photodetection tïpako o phenolsulfonyltransferase.Te whakatau pai o nga tohu waikawa-turanga, waikano, whakahiato pararopi, waipiro allyl, methanol, chloroform, me etahi atu. Waro monoxide, te waiwaro ngongo, te tohu rewharewha.
9. Manatokonga o te bromine, te chlorine, te chlorate, te niobium, te parahi, te nitrite me te pāhare pāporo;te whakatau i te waro monoxide, te parahi, te nitrite me te pāhare pāporo;te whakatau kounga o te waipiro allyl, te methanol, te chloroform, me etahi atu;phenolsulfon transferase Tïpako ine inenga;ethylene absorber;tohu rewharewha;tohu waikawa-papa;waikano takawaenga.

Tikanga whakaputa:
1. He mea hanga mai i te naphthalene na roto i te sulfonation me te whakakotahitanga alkali.Ko te tikanga whakangao alkali sulfonated he tikanga whakaputa i te kainga me nga whenua o waho, engari he nui te waikura, te utu nui, me te nui o te kohi hāora koiora i roto i te wai para.Ko te tikanga 2-isopropylnaphthalene i whakawhanakehia e te American Cyanamide Company e whakamahi ana i te naphthalene me te propylene hei rauemi mata hei whakaputa i te 2-naphthol hei hua-a-acetone.He rite tenei tikanga ki te hanga phenol ma te tikanga cumene.Te motunga kai maata: naphthalene parakore 1170kg/t, waikawa pungatara 1080kg/t, houra toka 700kg/t.

2.1) Tikanga whakakorewa kawakore whakawhaariki.Whakanohoia te naphthalene kua oti te para ki roto i te kohua sulfonation ka whakamahana (whakarewa) ki te 140°C.Tāpirihia kia 1.085 nga wa (molar ōwehenga) waikawa pungatara i roto i te 20 meneti, whakanuia te pāmahana, ka pupuri i te 160-164°C mo te 2.5 haora.Ka mutu te tauhohenga ina tae te ihirangi o te waikawa 2-naphthalenesulfonic ki te 66% neke atu ranei, ka 25%-27% te katoa o te waikawa.Ka whakamaua te sulfonate i roto i te kohua hauwai i te 140-150 ℃ mo te 1h.Na i roto i te kohua whakakore, whakakorehia ki te wairewa konutai hauwai nitrite i te 80-90°C kia kore ra ano te pepa whakamatautau whero o Congo e huri kikorangi.Whakamahia te mamaoa me te hau ki te pana atu i te hau SO2, whakamatao ki te 30-40°C katahi ka tātari momi, horoi ki te 10% wai tote, katahi ka tātari momi kia whiwhi konutai 2-naphthalenesulfonate.Whakanohoia te konutai waiwai ki roto i te kohua whakarewa kawakore, whakamahana (whakarewa) ki te 290°C, ka tapirihia te konutai 2-naphthalenesulfonate i roto i te 3 haora tae noa ki te 5%-6%.Muri iho, ka noho ki te 320-330°C mo te 1 haora.Ka waimeha te whakarewa alkali ki te wai ka tukuna te SO2 i te 70-80°C kia kore te tae o te phenolphthalein.Tāpirihia he wai ki te whewhe ka horoi, ka tango i te konutai sulfite, ka whakamakuku ka whakamakuku i raro i te pehanga iti kia whiwhi ai i te hua kua oti.Ko te hua katoa ko te 73%-74%.
2) tikanga 2-isopropylnaphthalene.Pukapuka matū, e whakamahi ana i te naphthalene me te propylene hei rauemi mata, ka whakaputa ano i te 2-naphthol i te wa ano hei hua-a-acetone.

3. Ko te tikanga whakarite ko te whakauru i te waikawa pungatara ki te naphthalene whakarewa i te 140°C, ka mahia te whakangao i te 162～164°C, te whakamaarama i te sulfonate, te pupuhi i te naphthalene kore utu, me te tauhohe ki te konutai sulfite ki te whakaputa 2-naphthalenesulfonic acid konutai tote .Ko te tote konutai totoka me te konutai konutai he kawakore-whakarewa i te 285-320°C, ka mau ki te 320-330°C mo te 1 haora.Ka waimeha te rewa kawakawa ka tukuna ki roto i te whanariki hauhā mo te waikawa kia puta mai he hua maru, ka horoia, ka whakamakukuhia, katahi ka maturu kia whiwhi ai te hua.

4. Te tikanga whakakorewatanga kawakawa whakangao sulfonation Kuhua te naphthalene parakore ki roto i te kohua sulfonation ka whakamahana (whakarewa) ki te 140°C.Tāpirihia kia 1.085 wa (te ōwehenga molar) te waikawa pungatara i roto i te 20 meneti, whakanuia te pāmahana, ka pupuri i te 160～164℃ mo te 2.5h.Ka mutu te tauhohenga ina tae te ihirangi o te waikawa 2-naphthalenesulfonic ki te 66% neke atu ranei, ka 25%-27% te katoa o te waikawa.Ka whakamarohia te sulfonate ki roto i te kohua hauwai i te 140～150 ℃ mo te 1 haora.Na i roto i te kohua whakakore, whakakorehia ki te otinga konutai bisulfite i te 80 ~ 90 ℃ kia kore ra ano te pepa whakamatautau whero o Congo e huri kikorangi.Whakamahia te mamaoa me te hau ki te pana atu i te hau SO2, whakamatao ki te 30-40°C katahi ka tātari momi, horoi ki te 10% wai tote, katahi ka tātari momi kia whiwhi konutai 2-naphthalenesulfonate.Whakanohoia te konutai waiwai ki roto i te kohua whakarewa kawakore, whakamahana (whakarewa) ki te 290°C, ka tapirihia te konutai 2-naphthalenesulfonate i roto i te 3 haora tae noa ki te 5% ki te 6%.I muri i tera, ka mau ki te 320-330°C mo te 1 haora.Ka waimeha te rewa kawa ki te wai ka paahitia te SO2 i te 70~80 ℃ kia kore te tae o te phenolphthalein.Tāpirihia he wai ki te whewhe ka horoi, ka tango i te konutai sulfite, ka whakamakuku ka whakamakuku i raro i te pehanga iti kia whiwhi ai i te hua kua oti.Ko te katoa o nga hua ko te 73% ki te 74%.Ko te tikanga 2-isopropylnaphthalene e whakamahi ana i te naphthalene me te propylene hei rauemi mata hei whakaputa i te 2-naphthol me te acetone-hua.

Rauemi mata whakarunga:konutai hauwai–>waikawa pūngāwhā–>waikawa hauota–>konutai pūngāwhārangi–>hauhā pāhare–>naphthalene–>pepa whakamātautau whero Congo–>wairewa konutai bisulfite–> waikawa 2-naphthalenesulfonic –>Phenolphthalein–> Konutai 2-naphthalenesulfonate–> Te houra kawa totoka

Nga hua o raro: 2-naphthylamine–>R-1,1′-bin-2-naphthol–>Pigment Whero 21–>2-naphthylamine-1-sulfonic acid–>naphthylamine–>S -1,1′-Bi-2-naphthol –>1-Amino-2-naphthol-4-sulfonic acid–>Acid Blue 74–>2-hydroxy-3-naphthoic acid–>2- Fluoronaphthalene–>6-Methoxy-2-acetnaphthalene–>chrome pango T–> 6-hydroxynaphthalene-2-boronic acid–>2-naphthol-3,6-disulfonic acid disodium- ->1-Naphthyldiazo-2-hydroxy-4-sulfonic acid tote roto–>2-Amino-8-naphthol-6- waikawa sulfonic–>Lithol Scarlet–> Pigment Whero 53:1 Chemicalbook –> Pigment Orange 5–> Pigment Whero 4–> Pigment Whero 3–> Mordant Black 17–> Naproxen–> Synthetic Tanning Agent HV–> Neutral Black 2S-RL –>Waenga Pango BL–>2-Naphthaleneboronic acid–>2-Hydroxy-1-naphthoic acid–>Sodium 6-hydroxy-2-naphthalenesulfonate–>N-phenyl-2-naphthylamine–>Synthesis Tanning agent PNC–>2- naphthylamine-3,6,8-trisulfonic acid–>bis[3-hydroxy-4-[(2-hydroxy-1-naphthyl)azo]-1-naphthalenesulfonate Disodium hydrogen chromate–>Sodium 3-hydroxy-4-[( 2-hydroxynaphthalene)azo]-7-nitronaphthalene-1-sulfonate–>SAgent Tanning ynthetic No. 9